COMPOSITIONAL ANALYSIS AND YIELD OPTIMIZATION OF XYLAN EXTRACTION FROM RENEWABLE AGRO-INDUSTRIAL WASTE
Main Article Content
Keywords
Corn husk, agro-industrial waste, hemicellulose, xylan
Abstract
Agro-industrial waste is mostly composed of biomass derived from lignocellulose. Lignocellulose waste has been receiving great interest due to its readily available nature, mechanical and thermal capabilities, cost-effectiveness, low toxicity, biodegradability and renewable qualities. Corn husk is a renewable lignocellulosic biomass resource with significant potential for sustainable development and agricultural waste utilization. It contains cellulose, hemicellulose and lignin components. The main component of hemicellulose is xylan that can be used as a raw material or an intermediate in food and non-food industries. Current investigation is based on the yield optimization of xylan extraction from renewable agro-industrial waste after the determination of compositional analysis of corn husk that showed the high amount of organic, cellulose and hemicellulose content in it. Furthermore, extraction of xylan from corn husk was done by using steam as a pretreatment method that weakened the link between lignin, cellulose and hemicellulose making xylan available for extraction. After pretreatment, 12% NaOH was used for xylan extraction that produced high yield followed by the determination of reducing sugars (63 % xylose, 23 % arabinose and 14 % glucose) in its structure.
References
2. American Association of Cereal Chemists (AACC). 2019. Approved methods of the Analysis. 11th Ed. Cereals & Grains Association, St. Paul, MN, U.S.A.
3. Anh, P. T. H. and D. M. Tai. 2024. Closer Approach towards the Preparation of Cellulose and Microcrystalline Cellulose from Corn Husks. Chemical Engineering & Technology. 47(9): 202300379.
4. Enawgaw, H., T. Tesfaye, K. T. Yilma and D. Y. Limeneh. 2023. Multiple Utilization Ways of Corn By-Products for Biomaterial Production with Bio-Refinery Concept; a Review. Materials Circular Economy. 5(1): 7-20.
5. Ibrahim, M., S. Sapuan, E. Zainudin and M. Zuhri. 2020. Preparation and characterization of cornhusk/sugar palm fiber reinforced Cornstarch-based hybrid composites. Journal of Materials Research and Technology. 9(1): 200-211.
6. Kambli, N. D., V. Mageshwaran, P. G. Patil, S. Saxena and R. R. Deshmukh. 2017. Synthesis and characterization of microcrystalline cellulose powder from corn husk fibres using bio-chemical route. Cellulose. 24: 5355-5369.
7. Khat-Udomkiri, N., B. S. Sivamaruthi, S. Sirilun, N. Lailerd, S. Peerajan and C. Chaiyasut. 2018. Optimization of alkaline pretreatment and enzymatic hydrolysis for the extraction of xylooligosaccharide from rice husk. AMB Express. 8: 1-10.
8. Kumari, K., S. Nagar, S. Goyal, S. Maan, V. Kumar, N. Kharor, M. Sindhu and V. Kumar. 2024. A fast, reliable, low‐cost, and efficient xylan extraction for xylooligosaccharides production. Biofuels, Bioproducts and Biorefining. 18(5): 1355-1368.
9. Mayta, S., R. G. Huamani-Palomino, B. M. Córdova, E. Rivera and M. Quintana. 2024. Utilizing peracetic acid as an eco-friendly bleaching agent: investigating whiteness levels of cellulose microfibers from corn husk waste. Biomass Conversion and Biorefinery. 1-13.
10. Mendes, C., F. Adnet, M. Leite, C. G. Furtado and A. Sousa. 2015. Chemical, physical, mechanical, thermal and morphological characterization of corn husk residue. Cellul. Chem. Technol. 49: 727-735.
11. Pereira, B. S., C. de Freitas, J. Contiero and M. Brienzo. 2022. Enzymatic production of xylooligosaccharides from xylan solubilized from food and agroindustrial waste. BioEnergy Research. 1-9.
12. Rajinipriya, M., M. Nagalakshmaiah, M. Robert and S. Elkoun. 2018. Importance of agricultural and industrial waste in the field of nanocellulose and recent industrial developments of wood based nanocellulose: a review. ACS Sustainable Chemistry & Engineering. 6(3): 2807-2828.
13. Ratna, A. S., A. Ghosh and S. Mukhopadhyay. 2022. Advances and prospects of corn husk as a sustainable material in composites and other technical applications. Journal of Cleaner Production. 371: 133563-133591.
14. Samanta, A. K., A. Kolte, A. Elangovan, A. Dhali, S. Senani, M. Sridhar, K. Suresh, N. Jayapal, C. Jayaram and S. Roy. 2016. Value addition of corn husks through enzymatic production of xylooligosaccharides. Brazilian Archives of Biology and Technology. 59: 16160078-16160085.
15. Samanta, A., S. Senani, A. P. Kolte, M. Sridhar, K. Sampath, N. Jayapal and A. Devi. 2012. Production and in vitro evaluation of xylooligosaccharides generated from corn cobs. Food and Bioproducts Processing. 90(3): 466-474.
16. Yan, F., S. Tian, K. Du, X. a. Xue, P. Gao and Z. Chen. 2022. Preparation and nutritional properties of xylooligosaccharide from agricultural and forestry byproducts: A comprehensive review. Frontiers in Nutrition. 9: 977548-977567.